SCIENCE OF COOKING
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SCIENCE OF PRESSURE COOKING

Pressure cooker image is that of a Kuhn Rickon

Pressure Definitions:

Pressure (symbol: P) is the force per unit area applied in a direction perpendicular to the surface of an object. The SI unit for pressure is the pascal (Pa), equal to one Newton per square meter (N/m2 or kg·m-1·s-2). Non-SI measures such as pound per square inch (psi) and bar are used in parts of the world. The cgs unit of pressure is the bar (ba), equal to 1 dyn·cm-2.

In US Customary units for pressure at sea level, it is 14.696 psi.

Pascal (Pa) bar atmosphere (atm) torr (Torr) pound-force per square inch (psi)
1 bar 1 N/m^2 10^6 dyn/cm^2 0.98692 750.06 14.5038

Example: A woman steps on you foot with a flat shoe one day... not too much pain. The next day she steps on your foot wearing a pointed high heel shoe... now much pain. Her weight did not change but the area where the force applied decreased substantially. Since pressure P is defined as Force/Area the pressure applied to the area of the foot is much higher.

This description of pressure helps explain why in the case of pressure cookers it does not take much weight (or force of a spring) to control the pressure when a small hole used.

History:

The first pressure cooker appeared in France in 1679 introduced as Papin’s Digester, named for its inventor, the French-born physicist Denis Papin. The cooker heated water to produce very hot steam which forced the temperature inside the pot as high as 266° F (130° C), higher than today's kitchen pressure cookers.

The first commercial pressure cooker debuted in the United States at the New York World's Fair in 1939, made by National Presto Industries. It's defined as a saucepan with a locking lid that creates within intense steam heat to cook foods in a shorter period of time than a conventional saucepan.The first patent

food. Then someone came up with the idea of making large (50 gallon) pressure cookers to be used for cooking by large businesses and institutions such as hotels, restaurants and schools. The first US pressure cooker patents were issued in 1902. The term 'pressure cooker' first appeared in print in 1915 and by 1917 the US Department of Agriculture determined that pressure canning was the only safe method of preserving low acid foods and meats without risking food poisoning

Then in 1939 the company introduced the first saucepan-style pressure cooker and gave it the trade name 'Presto 'to signify the speed of pressure-cooking. The 'Presto 'brand soon became synonymous with pressure-cooking and eventually the company changed its name to 'National Presto Company's which you probably know today simply as the Presto Company. In 1945 they introduced the first truly home-use pressure cooker which, at 4 quarts, was big enough to cook a meal but small enough to be manageable by the average housewife

Early pressure cookers did not have sufficient safety mechanisms and the risk for explosion was high. Today's modern day pressure cookers can have several pressure release valve mechanisms are are very safe if used according to manufacturers instructions.

How do Pressure Cookers Work?

Normally water will boil at 212F (100C) at sea level Atmospheric pressure at 1,01325 bar, i.e. normal atmospheric pressure on the sea level at 0°C --'in an open system'. At this temperature liquid water turns to gas. Applying more heat to an open pot of water will only increase the rate that liquid water turns to vapor but will not increase the temperature of the liquid.

If the pressure is decreased (e.g., at higher elevations) the point that water boils will be decreased (since it is easier for water molecules to escape the surface). If we increase the pressure on water it becomes more difficult for water molecules to escape the surface and a higher temperature is required for the water to boil.

In a closed container things change. The water and vapor are in equilibrium and will maintain the same temperature. With no place to escape if heat is applied to the closed container the molecules in the gas state will increase velocity, hence temperature. This will increase the pressure on the surface of the liquid. And, the temperature of the water system will then increase.

Gas Laws

The Ideal gas law is the equation of state of a hypothetical ideal gas. It is a good approximation to the behavior of many gases under many conditions, although it has several limitations. Still it simply shows how at constant volume increasing pressure will increase the temperature of the gas.

p is the absolute pressure of the gas;
V is the volume of the gas; n is the amount of substance of the gas, usually measured in moles;
R is the gas constant
T is the absolute temperature.

The ideal gas law does not however take into account the behavior of real fluids -- the nonzero size of molecules and the attraction between them. For this one must use the van der Waals equation derived by Johannes Diderik van der Waals in 1873, who received the Nobel prize in 1910 for "his work on the equation of state for gases and liquids". These equations predict the behavior of both gas and liquid states which exist within the pressure cooker.

Van der Waals first form  
p is the pressure of the fluid
v is the volume of the container holding the particles divided by the total number of particles
k is Boltzmann's constant
T is the absolute temperature
a' is a measure for the attraction between the particles
b' is the average volume excluded from v by a particle
Upon introduction of the Avogadro constant NA, the number of moles n, and the total number of particles n NA, the equation can be put into the second (better known) form Van der Waals second form  
p is the pressure of the fluid
V is the total volume of the container containing the fluid a is a measure of the attraction between the particles
b is the volume excluded by a mole of particles n is the number of moles
R is the universal gas constant,
T is the absolute temperature

Maillard Reaction and Pressure Cooking

The Maillard Reaction is what causes food to brown and gives that nice flavor. While the Maillard reaction can even take place at room temperature it starts to take off at temperatures above 250F. So there should be a greater amount of Maillard reaction ocurring during pressure cooking than normal simmering of stocks and stews. This is clearly verified when viewing and tasting stocks cooked using a pressure cooker.

Pressure Cooker Advantages:

-- Steam cooks many foods quicker than dry cooking methods.
-- makes excellent sauces after sautéing by dissolving products of caramelization and mallaird reaction
--works well with foods that require water infusion/braising methods
--foods that are steamed retain more nutrients and vitamins and flavor
--higher temperatures more effective at killing bacteria and viruses
--saves money since works on very low flame

Pressure Cooker Disadvantages:

-- takes time to heat liquid and time for pressure to be released so foods that cook within 15 minutes does not really save time.
-- cooks using water so foods that benefit by high heat (maillard reaction) will not produce desirable effects
--everything has to be cooked at the same time
--care must be taken when pressure is released
--while some Maillard reaction occurs food still has a steamed taste unless sufficient browning is done before or after cooking,

 

--What foods are best cooked using a pressure cooker?

Braising tough cuts of meat -- When cooking meat make sure to sear the meat first just as you would do when braising.

Beans --Pressure cooking beans is fast and easy, but it's important to oil when doing so to keeps the beans from foaming up as well as keeping the skins from popping. Beans can have a tendency to clock the air vents so be sure to clean properly after cooking beans.

Artichokes -- Making artichokes using a pressure cooker is fairly simple, and they come out perfectly cooked and very delicious.

Stocks -- According to Heston Blumenthal of the Fat Duck --..."at the Fat Duck we've just started using a brilliant gadget to make stocks. It's not exactly cutting-edge - it's the humble pressure cooker - but it makes stock better and quicker than any other method I know of..."

Under cooking and over cooking foods with the pressure cooker.

One of the problems you will encounter if just starting with a new pressure cooking is the times used to cook food. It is best therefore to abide by the times recommended by the manufacturer since pressure cookers will vary from one to another. A good rule of thumb is it is better to undercook than overcook since you can always increase time.

--Recipes using the Kuhn Rikon Pressure Cooker

Osso Bucco with Red Wine Sauce and Polenta using a Pressure Cooker

 

References and Selected Readings:

How does a Pressure Cooker work-- Miss Vicki

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